S.C. Code Regs. When are dangerous goods safety marks required? Browse our full range of workplace health and safety products and services. Example: ETHANOL SOLUTION with more than 24% ethanol, by volume (UN1170). Class 2.1 Dangerous Goods WebMercury General Corporation is a multiple-line insurance organization offering personal automobile, homeowners, renters and business insurance. CCOHS is not liable for any loss, claim, or demand arising directly or indirectly from any use or reliance upon the information. Scheduled maintenance - Thursday, July 12 at 5:00 PM Except for Class 1, Explosives; UN numbers are only required for: those dangerous goods that must have an ERAP dangerous goods that are liquid or gas in direct contact with the large means of containment. Classification can be done by a consultant or a competent employee who has been trained in TDG classification. (2) Hazardous materials and hazardous substances transported by highway considered household wastes as defined in 40 CFR 261.4, and not subject to the Environmental Protection Agency's hazardous waste regulations in 40 CFR parts 262 and 263, are excepted from the requirements of this paragraph. Select country for which that subsidiary belongs to. Peroxides. For example: the mixture is liquid and homogeneous and the ingredients will not separate (e.g., no visible solids or two different phases such as you would observe when oil and water are mixed). Transportation of Dangerous Goods (TDG) - Classification, All White asbestos (chrysotile, actinolite, anthophyllite, tremolite), Dangerous Goods of Class9, Packing Group III, Liquids, not listed above, Dangerous Goods of Class9, Packing GroupIII, Solids, not listed above. For example: UN 1993, Flammable liquids, n.o.s. entries are assigned with special provisions 274 or 318 (see column 6 in the example below). Always checkwith Transport Canada andtheTDG Act and Regulationstoensure compliance. Code. Figure 3: Placard requirement and placement for a single dangerous good transported in a highway tank Image from Transport Canada. will be unavailable during this time. For example, both gasoline and diesel are listed by their name in Schedule 1. Placard for the subsidiary hazard class (if any) next to the primary hazard class placard on each side and each end (total of four) for: Each dangerous good that must have an ERAP. size of the means of containment (e.g., small vs. large). Mercury. It exists in several forms: Elemental (metallic) mercury. See Column 4 in Schedule 1. Code 246-231-140 - 246-231-140 - Advance notification of shipment of irradiated reactor fuel and nuclear waste. Specific chemical name (e.g., acetone, sulfuric acid, etc. Who is responsible for classifying a dangerous good? (6) For transportation by aircraft, the total net mass per package, must be shown unless a gross mass is indicated in Columns (9A) or (9B) of the 172.101 table in which case the total gross mass per package must be shown; or, for Class 7 materials, the quantity of radioactive material must be shown by activity. The subsidiary hazard class or division number is not required to be entered when a corresponding subsidiary hazard label is not required. When shipping marine pollutants by sea, the proper shipping name shall be be supplemented with the technical name of the marine pollutant. We expect this update to take about an hour. This placard is not mandatory, but it is permitted on a large means of containment (greater than 450 L) instead of any other placard when the containment has: - one or more dangerous goods that require different hazard class placards, - the dangerous goods are contained in two or more small means of containment, AND - the shipment consists of only the following dangerous goods classified in: NOTE: The TDG Regulations has specified circumstances when this placard is not allowed to be used. The are classified in the Class 1 hazard class. The rules are set out in a table, the segregation table in 7.2.4, and also have to be applied in respect of any subsidiary class. A placard is used for a large means of containment whose capacity is more than 450 L. The marks for safety for each TDG class are shown in the OSH Answers document Transportation of Dangerous Goods (TDG) - 9 Classes. 6 CCR 1007-1 Part 17 - 6 CCR 1007-1 Part 17 - RADIATION CONTROL - TRANSPORTATION OF RADIOACTIVE MATERIALS, GA Reg. See the example below. Oxidizing 6. The letters UN must not be included with the number when the UN number is displayed on the primary class label. They are preferred in the following order: If you cannot find a good match in 1, you move to 2, 3 and 4 by order. If you are a consultant, you may get yourself listed in CSP business directory (free) or Your product may meet the criteria for one or more of the of the following nine TDG hazard classes: If your product meets the criteria for several hazard classes, the primary class must be determined. Self-heating solid, corrosive, organic, n.o.s. (b) for a liquefied petroleum gas that has not been odorized, the words Not Odourized or Not Odorized or Sans odorisant. See Section 2.4. Elevated temperature solid, n.o.s., at or above 240C (464F). Being on this list does not mean Transport Canada or the TDG Directorate endorses or approves their services. CHLORINE DIOXIDE is an example of a product that is forbidden by all routes of transportation as indicated in Schedule 3 with an entry of Forbidden in Column 2 - Hazard Class. International Civil Aviation Organization (ICAO) Technical Instructions for the transport of dangerous goods by air, International Maritime Dangerous Goods (IMDG) Code for the transport of dangerous goods by ship, or. Abbreviations may be used for indicating packaging types (for example, cyl. for cylinder) provided the abbreviations are commonly accepted and recognizable. Note: The information below is provided as guidance only. Image from Transport Canada. Flammable Gases 3. Laboratory tests are required for pure substances, solutions, and mixtures. EDT. Code Regs. If you have questions or need any help, please contact our sponsor. Class 3 Packing Group III. 1273 0 obj <> endobj When the dangerous goods safety marks are, primary class label and each subsidiary class label for each of the dangerous goods, as well as the shipping name and UN number, must be displayed on the overpack, the word overpack is required on at least one side for overpacks with capacity less than 1.8 m3 (64 cubic feet), the words overpack on at least two opposite, required to display subsidiary hazard class placard. WebClasses 1 to 9 Col. 1 Col. 2 Col. 3 Col. 4 Col. 5 Col. 6 Col. 7 Col. 8 Col. 9 Col. 10 UN Number Shipping Name and Description Class Packing Group/ Category SOR/2008-34 MERCURY FULMINATE, WETTED with not less than 20 per cent water, or mixture of alcohol and water, by mass 1.1A UN0136 II 0 75 Forbidden Forbidden There may be occasions when several different shipping names can be used. Abbreviations may be used to express units of measurement and types of packagings. (drazoxolon). Depending on the classification for a dangerous good, one or more of the following safety marks may be required on a large means of containment: NOTE: Generally speaking, a placard must be displayed for each of the dangerous goods transported in a large means of containment regardless of the quantity. The Proper Shipping Name shall be supplemented with "MOLTEN"; Stabilized substances: If you have questions or need any help, please contact our sponsor. Mercury's surface temperatures are Meanwhile the actual assigned category is obtained from Appendix 3 in Part 2. For example, based on the above information from Schedule 1 we have the following information for UN1203: Schedules 1 and 3 will also indicate if any shipping routes are forbidden. If the dangerous good is an explosive or radioactive material, it must be classified as required by other regulatory authorities. Product usage (e.g., pesticide, adhesive, fuel, etc. Some manufacturing is in Fond du Lac, while 40-60 HP motors are made in China. (cadmium sulfide, isodecyl diphenyl phosphate), 9, III, Marine Pollutant. These are the primary class 2.3 and two subsidiary hazard classes 5.1 and 8. Class 4 Substances/Products include: Flammable Solids; Substances Liable to Spontaneous Combustion; Substances That on Contact with Water Emit Flammable Gases (Water-reactive Substances), Class 5 Oxidizing Substances, including Organic Peroxides, Class 9 Miscellaneous Products, Substances or Organisms. This mark is displayed on small means of containment filled with infectious substances that are assigned to UN3373, Biological Substance Category B. It would be shipped as "UN 2809, MERCURY, 8(6.1)" and assigned to Packing Group II. The subsidiary class is the other class that further identifies the hazards of the dangerous goods. The material's flash point will be displayed with the unit of measure and followed by "c.c." The alphabetical order has been determined by ignoring all numerical digits and all lower case letters that precede the first capital letter in the shipping name. Access to this website as appropriate. Mercury is a metallic element released into the air as a vapour by natural processes and anthropogenic activities. The required markings for overpacks include: Placards are not required for consolidation bins as the definition and description for a consolidation bin does not include large means of containment. 61-63 - 61-63 - Radioactive Materials (Title A). Definition for a solution When the ingredients in a mixture are completely dissolved. Please also see the following documents in this series: The purpose of dangerous goods safety marks is to: Dangerous goods safety marks are required when the good that is being transported: The TDG Regulations (Part 4) specify that all safety marks must be: Responsibilities for dangerous goods safety marks depend on whether the handler of the dangerous goods is the: Before the goods are loaded on the means of transport (i.e., vehicle, truck), the consignor or importer must: Misleading safety marks are dangerous goods safety marks that might be deceptive, ambiguous, or provide false information about the presence or nature of any dangers. Selecting a correct proper shipping name is not easy. Consult Schedule 3 for the shipping name that most precisely describes the dangerous goods. Note that the TDG Directorate has not examined or certified any of the laboratories. A label is used for a small means of containment whose capacity is 450 L or less. 33, Part XV, 1519 - 1519 - Advance Notification of Shipment of Irradiated Reactor Fuel and Nuclear Waste [Formerly 1516], 10 144 Me. Dangerous goods safety marks are the first line of communication about the hazard(s) of the dangerous good. A substance, mixture, or article that is a marine pollutant and does not meet the classification criteria for inclusion in any other hazard class shall be declared under either UN 3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, n.o.s. Use the descriptive text written in lower case letters following a shipping name (see the example for UN1337 below) to determine the shipping name that most precisely describes the dangerous goods. It can be either a tag or a fixed display device (white board or a piece of paper) that will be updated every time a dangerous good is removed or added (Section 4.10.2 in the TDG Regulations). Figure 3: Labels on cylinders. UN3091 or UN3481, as appropriate for lithium cells or batteries that are contained in, or packed with equipment. (ii) The hazard class need not be included for the entry Combustible liquid, n.o.s.. endobj (ii) For hazardous materials in salvage packaging, an estimate of the total quantity is acceptable. WebMercury Factsheet. TN Rules and Regs. Substances (including substances and mixtures), and articles are assigned to one of the following 9 classes according to the most predominant hazards they pose in transport. Figure 2: Safety marks on a small means of containment such as a package Note 1: The orientation marks for liquids are optional for road transport, but mandatory for air transport. WebMercury (Metallic) Quicksilver; Hydrargyrum; Liquid Silver 1.2. Wastes: If the product is a waste, then the shipping name is either preceded or followed by the word waste. Placards are not required or are optional for some dangerous goods when the gross quantity of the dangerous goods is 500 kg or less. WebIf a type 3 vessel carrying Class 1 DG on board would staying over-night at the WDGA, notification in writing to the Dangerous Goods Unit of the Marine Department will need to be given. Alkalis. If the product has already been classified, the consignor may use the TDG classification of the manufacturer or a previous consignor. Also, regardless of the quantity of dangerous goods on board, the primary class placard for each of the dangerous goods in a large means of containment must be displayed on each side and on each end of the large means of containment or means of transport. Class1.1, 1.2, 1.3 or 1.5 explosives that are: not subject to Special Provision 85 or 86 and the quantity is less than or equal to 10 kg, or, subject to Special Provision SP 85 or 86 and the quantity is less than or equal to 1000 articles (note: this is number of articles, not mass), Class 1.4 (except Class 1.4S) is 1000 kg or less, Class 6.1 and are not required to comply with Special Provision 23, Class 6.1 but are not an inhalation hazard and are not listed in Special Provision 23. capacity of each cylinder is greater than 225 L, are interconnected through a piping arrangement, and, are permanently mounted on a structural frame for transport, Class 6.1 for exposure to other routes (not an inhalation hazard)and are not listed in Special Provision 23, Class 6.1, Toxic Substances due to inhalation toxicity, Are dangerous goods subject to Special Provision 23. Packing Group This column gives the packing groups of the dangerous goods. ), MARINE POLLUTANT. Dangerous goods can present 1 or more of the hazards represented by Class 1 to 9 with some classes split into divisions. Identification number - UN Number must be displayed within a white rectangle located on the primary class label itself or next to the primary class. Some dangerous goods have multiple hazards. (e) Except for those materials in the UN Recommendations, the ICAO Technical Instructions, or the IMDG Code (IBR, see 171.7 of this subchapter), a material that is not a hazardous material according to this subchapter may not be offered for transportation or transported when its description on a shipping paper includes a hazard class or an identification number specified in the 172.101 Table. a person capable of understanding the nature of the dangerous good (e.g., manufacturer's professional employees such as a chemical engineer, chemist, scientist, etc. Chemical family name (e.g., alcohol, ketone, etc. b) The laboratory test results show the product falls into one class and one packing group. On the periodic table, it has the symbol "Hg" and its atomic number is 80. Download the OSH Answers app for free. Admin. This sign must be displayed at or next to each entry way of the large means of containment (greater than 450 L) when the containment is fumigated with a dangerous good. What safety marks are required on a large means of containment (capacity 450L or more)? Generic risk (e.g., flammable, toxic, etc.). Class 1 (explosives) materials; self-reactive substances; Division 5.2 materials; and entries that are not assigned a packing group (e.g., Class 7) are excepted from this requirement. Yes. There are other considerations for some special dangerous goods, for which additional description words shall be added. For example: UN1993, FLAMMABLE LIQUID, N.O.S. Are safety marks required on consolidation bins? If a small means of containment is placed inside another, and the outer container is not opened during loading, transport or unloading, the label is required only on the outer small means of containment. How do I determine the identification number / UN Number? ?O.Q\tF,"V4Iuu8jhb7ew?NI ~eS^lsEU_{\3>e; F]u:MvF7Bz3Jz;O>tzw5qy:!&|]&$fG6F`B@a'\` Eno14}tQ`?K4%1nFh,D_Qg4f>~j $7NH s:o~P;v4fRd%r{6|;>v&K >Z!O~X}u!wv=@~0}$vN=. View Past Newsletter, Class 4 Flammable solids; substances liable to spontaneous combustion; substances which, in contact with water, emit flammable gases, Class 5 Oxidizing substances and organic peroxides, Class 9 Miscellaneous dangerous substances and articles, including environmentally hazardous substances, Biocides and Biocidal Product Regulations, I (High Danger) > II (Medium Danger) > III (Low Danger), Materials of class 7 (except radio-active materials in excepted packages), Liquid desensitised explosives of class 3, Self-reactive substances and solid desensitised explosives of division 4.1, Substances of division 6.1 or class 3 with packing group I by inhalation. %%EOF if applicable, the classification method used under Part 2 of the TDG Regulations or under Chapter 2 of the UN Recommendations. NOTE: The size of the Inhalation hazard letters vary for different types of means of containment. (v) the subsidiary class or classes, in parentheses, which may be shown as a number only or under the heading subsidiary class or classe subsidiaire or following the words subsidiary class or classe subsidiaire, except that, for transport by aircraft or by ship, the subsidiary class or classes may be shown after the information required by this paragraph, (vi) the packing group roman numeral, which may be shown under the heading PG or GE or following the letters PG or GE or following the words Packing Group or Groupe d'emballage, and. endstream endobj startxref <> Inhalation Hazard words for Class 6.1 and Class 2.3 dangerous goods, Category B Mark for UN3373 dangerous goods, Package certification marks (if required), Placard for the primary hazard class on each side and each end (total of four) for each dangerous good. WebClassification of dangerous goods is broken down into nine classes according to the type of danger materials or items present, click on a class to read more details; 1. Is "Waste", "Molten", "Stabilized", "Flash point", "Marine Pollutant" applicable. It can cause headaches, can damage the nervous system of the body. << How do I determine the compatibility group? Scheduled maintenance - Thursday, July 12 at 5:00 PM Column 5 Packing Group Contains the packing group number (i.e. If you cannot get through, please contact us by email. 82-4-3k - 82-4-3k - Transportation of hazardous materials; driving and parking rules, La. Note 2: Package certification safety marks are specified in the standard that the package or container is compliant with. That legal outcome opened the door to hire a new design and construction team to finish the North Course. Column 3 Class or Division Contains the class and, in the case of class 1, the division and compatibility group. (iii) The following are excepted from the requirements of paragraph (a)(5) of this section: (A) Bulk packages, provided some indication of the total quantity is shown, for example, 1 cargo tank or 2 IBCs., (B) Cylinders, provided some indication of the total quantity is shown, for example, 10 cylinders.. Developed by Mercury and its joint venture company Cummins MerCruiser Diesel (CMD), the Zeus drive is a dual Large means of containment: These words must be displayed on two opposite sides of the large means of containment in addition to any other safety marks that are required under the TDG Regulations. Hazard class (the primary class and possible subsidiary class/es), Packing group, compatibility group, or the infectious substance category for biohazardous substances, SHIPPING NAME (in Column 2 of Schedule 1): GASOLINE; MOTOR SPIRIT; or PETROL (when selecting the shipping name you can use one of the three listed names such as gasoline), Hazard Class (in Column 3 of Schedule 1): 3, Identification Number (in Column 1 of Schedule 1): UN1203, Packing Group (in Column 4 of Schedule 1): II, UN1096 SIGNALS, SMOKE which is not allowed to be transported on a ship. For example, UN3518 ADSORBED GAS, TOXIC, OXIDIZING, CORROSIVE, N.O.S. has three hazard classes assigned to it in Column 3 of Schedule 1. The type of packaging and destination marks may be entered in any appropriate manner before or after the basic description. Are there other requirements for labels on a small means of containment? or UN 3082 ENVIRONMENTALLY HAZARODUS SUBSTANCE, LIQUID, n.o.s. Flammable Liquids 4. Toxic & Infectious 7. classified in Class 2.3, Toxic Gases hazard class, classified in Class 4.3, Water-reactive Substances hazard class and all packing groups, classified in Class 5.2, Organic Peroxides (Type B, liquid or solid, that require control temperature.) For articles (e.g., UN2800 and UN3166) the quantity must be the gross mass, followed by the letter G; and. Has a subsidiary classification of Class 1 (1.1,1.2, 1.3 above the exemption limits), Class 4.3, Class 6.1 (Packing Group I), Class 8 (applies only to UN numbers The Proper Shipping Name must be preceded by the word "WASTE"; Solid transported in a molten state: The labelling requirements for an overpack depend on whether the labels can be seen through the overpack. As such, the mixture would be assigned the shipping name FLAMMABLE LIQUID, N.O.S.. Column 4 Subsidiary Risk(s) Contains the class number(s) of any subsidiary risk(s). 1 0 obj See Section 4.10(5) in the TDG Regulations for circumstances when labels are not required and the "Packaging and Transport of Nuclear Substances Regulations" for specific marking requirements. Corrosives 9. Nitrites and their mixtures. The following provisions also apply: (i) For empty uncleaned packaging, only the number and type of packaging must be shown; (ii) For chemical kits and first aid kits, the total net mass of hazardous materials must be shown.

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what is subsidiary class for mercury

what is subsidiary class for mercury